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anditomin biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
preandiloid_A + acceptor <=> preandiloid_B + reduced_acceptor 1.1.99

preandiloid_B + acceptor <=> preandiloid_C + reduced_acceptor 1.1.99

5,7-dihydroxy-4,6-dimethylphthalide + (2E,6E)-farnesyl_diphosphate <=> farnesyl-5,7-dihydroxy-4,6-dimethylphthalide + diphosphate 2.5.1

acetyl-andilesin_A <=> andilesin_B + acetate + H+ not assigned

farnesyl-5,7-dihydroxy-4,6-dimethylphthalide + O2 + reduced_acceptor <=> epoxyfarnesyl-5,7-dihydroxy-4,6-dimethylphthalide + H2O + acceptor 1.14.13

andilesin_A + acceptor <=> andilesin_D + reduced_acceptor 1.1.99

andiconin + O2 + NADPH + H+ <=> andilesin_D + NADP+ + H2O 1.14.13

preandiloid_C + 2-oxoglutarate + ascorbate + O2 <=> andiconin + succinate + CO2 + dehydroascorbate + H2O 1.14.20

4,6-dihydroxy-2-(hydroxymethyl)-3,5-dimethylbenzoate + H+ <=> 5,7-dihydroxy-4,6-dimethylphthalide + H2O 3.1.1

epoxyfarnesyl-5,7-dihydroxy-4,6-dimethylphthalide <=> preandiloid_A 5.4.99

3,5-dimethylorsellinate + O2 + reduced_acceptor <=> 4,6-dihydroxy-2-(hydroxymethyl)-3,5-dimethylbenzoate + H2O + acceptor 1.14.99

andilesin_C + 2-oxoglutarate + O2 <=> anditomin + succinate + CO2 + H2O 1.14.20

andilesin_B + reduced_acceptor <=> andilesin_C + acceptor 1.1.99

S-adenosyl-L-methionine + acetyl-CoA + malonyl-CoA <=> 3,5-dimethylorsellinate + S-adenosyl-L-homocysteine + CO2 + CoA 2.3.1

andilesin_A + acetyl-CoA <=> acetyl-andilesin_A + CoA 2.3.1

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